Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 박진병 | * |
dc.contributor.author | 권용억 | * |
dc.date.accessioned | 2020-04-13T16:30:18Z | - |
dc.date.available | 2020-04-13T16:30:18Z | - |
dc.date.issued | 2020 | * |
dc.identifier.issn | 1433-7851 | * |
dc.identifier.other | OAK-26714 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/253791 | - |
dc.description.abstract | Long-chain aliphatic amines such as (S,Z)-heptadec-9-en-7-amine and 9-aminoheptadecane were synthesized from ricinoleic acid and oleic acid, respectively, by whole-cell cascade reactions using the combination of an alcohol dehydrogenase (ADH) from Micrococcus luteus, an engineered amine transaminase from Vibrio fluvialis (Vf-ATA), and a photoactivated decarboxylase from Chlorella variabilis NC64A (Cv-FAP) in a one-pot process. In addition, long chain aliphatic esters such as 10-(heptanoyloxy)dec-8-ene and octylnonanoate were prepared from ricinoleic acid and oleic acid, respectively, by using the combination of the ADH, a Baeyer–Villiger monooxygenase variant from Pseudomonas putida KT2440, and the Cv-FAP. The target compounds were produced at rates of up to 37 U g−1 dry cells with conversions up to 90 %. Therefore, this study contributes to the preparation of industrially relevant long-chain aliphatic chiral amines and esters from renewable fatty acid resources. © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | * |
dc.language | English | * |
dc.publisher | Wiley-VCH Verlag | * |
dc.subject | Biocatalysis | * |
dc.subject | fatty acids | * |
dc.subject | long-chain aliphatic amines | * |
dc.subject | photodecarboxylase | * |
dc.subject | whole-cell biocatalysis | * |
dc.title | Whole-Cell Photoenzymatic Cascades to Synthesize Long-Chain Aliphatic Amines and Esters from Renewable Fatty Acids | * |
dc.type | Article | * |
dc.relation.issue | 18 | * |
dc.relation.volume | 59 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 7024 | * |
dc.relation.lastpage | 7028 | * |
dc.relation.journaltitle | Angewandte Chemie - International Edition | * |
dc.identifier.doi | 10.1002/anie.201915108 | * |
dc.identifier.wosid | WOS:000515398800001 | * |
dc.identifier.scopusid | 2-s2.0-85083689682 | * |
dc.author.google | Cha H.-J. | * |
dc.author.google | Hwang S.-Y. | * |
dc.author.google | Lee D.-S. | * |
dc.author.google | Kumar A.R. | * |
dc.author.google | Kwon Y.-U. | * |
dc.author.google | Voß M. | * |
dc.author.google | Schuiten E. | * |
dc.author.google | Bornscheuer U.T. | * |
dc.author.google | Hollmann F. | * |
dc.author.google | Oh D.-K. | * |
dc.author.google | Park J.-B. | * |
dc.contributor.scopusid | 박진병(15036390700) | * |
dc.contributor.scopusid | 권용억(7403459303) | * |
dc.date.modifydate | 20240322114808 | * |