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Isotopic variations of meltwater from ice by isotopic exchange between liquid water and ice

Title
Isotopic variations of meltwater from ice by isotopic exchange between liquid water and ice
Authors
Ham, Ji-YoungHur, SoonLee, Won SangHan, YeongcheolJung, HyejungLee, Jeonghoon
Ewha Authors
이정훈
SCOPUS Author ID
이정훈scopus
Issue Date
2019
Journal Title
JOURNAL OF GLACIOLOGY
ISSN
0022-1430JCR Link

1727-5652JCR Link
Citation
JOURNAL OF GLACIOLOGY vol. 65, no. 254, pp. 1035 - 1043
Keywords
Ice chemistryice coremeltwater chemistry
Publisher
CAMBRIDGE UNIV PRESS
Indexed
SCI; SCIE; SCOPUS WOS
Document Type
Article
Abstract
Predicting the isotopic modification of ice by melting processes is important for improving the accuracy in paleoclimate reconstruction. To this end, we present results from cold room laboratory observations of changes in the isotopic ratio (D/H and O-18/O-16) of ice cubes by isotopic exchange between liquid water and ice in nearly isothermal conditions. A 1-D model was fit to the isotopic results by adjusting the values of two parameters, the isotopic exchange rate constant (k(r)) and the fraction of ice participating in the exchange (f). We found that the rate constant for hydrogen isotopic exchange between liquid water and ice may be greater (up to 40%) than that for the oxygen isotopic exchange. The range of the rate constant obtained from four melt experiments is from 0.21 to 0.82 h(-1). The model results also suggest that f decreases with the increasing wetness of the ice. This is because with increasing water saturation in ice, water may be present only in the small pores or some of the water that was exchanged with ice may be bypassed, decreasing the effective surface area over which the isotopic exchange can occur. The relationship between the two water isotopes (delta O-18 vs delta D) was observed and modeled and the slope was <8, which is significantly different from the slope of the meteoric waterline. We note that these slopes were obtained without considering the sublimation process.
DOI
10.1017/jog.2019.75
Appears in Collections:
사범대학 > 과학교육과 > Journal papers
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