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Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex

Title
Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex
Authors
Hong S.Lu X.Lee Y.-M.Seo M.S.Ohta T.Ogura T.Clémancey M.Maldivi P.Latour J.-M.Sarangi R.Nam W.
Ewha Authors
남원우
SCOPUS Author ID
남원우scopus
Issue Date
2017
Journal Title
Journal of the American Chemical Society
ISSN
0002-7863JCR Link
Citation
vol. 139, no. 41, pp. 14372 - 14375
Publisher
American Chemical Society
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [FeV(NTs)(TAML)]- (1), was oxidized by one-electron oxidants, affording formation of an iron(V)-imido TAML cation radical species, [FeV(NTs)(TAML+•)] (2); 2 is a diamagnetic (S = 0) complex, resulting from the antiferromagnetic coupling of the low-spin iron(V) ion (S = 1/2) with the one-electron oxidized ligand (TAML+•). 2 is a competent oxidant in C-H bond functionalization and nitrene transfer reaction, showing that the reactivity of 2 is greater than that of 1. © 2017 American Chemical Society.
DOI
10.1021/jacs.7b08161
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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