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자연과학대학
화학·나노과학전공
Journal papers
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Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex
Title
Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex
Authors
Hong S.
;
Lu X.
;
Lee Y.-M.
;
Seo M.S.
;
Ohta T.
;
Ogura T.
;
Clémancey M.
;
Maldivi P.
;
Latour J.-M.
;
Sarangi R.
;
Nam W.
Ewha Authors
남원우
SCOPUS Author ID
남원우
Issue Date
2017
Journal Title
Journal of the American Chemical Society
ISSN
0002-7863
Citation
Journal of the American Chemical Society vol. 139, no. 41, pp. 14372 - 14375
Publisher
American Chemical Society
Indexed
SCIE; SCOPUS
Document Type
Article
Abstract
A mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [FeV(NTs)(TAML)]- (1), was oxidized by one-electron oxidants, affording formation of an iron(V)-imido TAML cation radical species, [FeV(NTs)(TAML+•)] (2); 2 is a diamagnetic (S = 0) complex, resulting from the antiferromagnetic coupling of the low-spin iron(V) ion (S = 1/2) with the one-electron oxidized ligand (TAML+•). 2 is a competent oxidant in C-H bond functionalization and nitrene transfer reaction, showing that the reactivity of 2 is greater than that of 1. © 2017 American Chemical Society.
DOI
10.1021/jacs.7b08161
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