Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.date.accessioned | 2017-12-27T16:30:48Z | - |
dc.date.available | 2017-12-27T16:30:48Z | - |
dc.date.issued | 2017 | * |
dc.identifier.issn | 0002-7863 | * |
dc.identifier.other | OAK-21517 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/239370 | - |
dc.description.abstract | A mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [FeV(NTs)(TAML)]- (1), was oxidized by one-electron oxidants, affording formation of an iron(V)-imido TAML cation radical species, [FeV(NTs)(TAML+•)] (2); 2 is a diamagnetic (S = 0) complex, resulting from the antiferromagnetic coupling of the low-spin iron(V) ion (S = 1/2) with the one-electron oxidized ligand (TAML+•). 2 is a competent oxidant in C-H bond functionalization and nitrene transfer reaction, showing that the reactivity of 2 is greater than that of 1. © 2017 American Chemical Society. | * |
dc.language | English | * |
dc.publisher | American Chemical Society | * |
dc.title | Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex | * |
dc.type | Article | * |
dc.relation.issue | 41 | * |
dc.relation.volume | 139 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 14372 | * |
dc.relation.lastpage | 14375 | * |
dc.relation.journaltitle | Journal of the American Chemical Society | * |
dc.identifier.doi | 10.1021/jacs.7b08161 | * |
dc.identifier.wosid | WOS:000413503300011 | * |
dc.identifier.scopusid | 2-s2.0-85031759744 | * |
dc.author.google | Hong S. | * |
dc.author.google | Lu X. | * |
dc.author.google | Lee Y.-M. | * |
dc.author.google | Seo M.S. | * |
dc.author.google | Ohta T. | * |
dc.author.google | Ogura T. | * |
dc.author.google | Clémancey M. | * |
dc.author.google | Maldivi P. | * |
dc.author.google | Latour J.-M. | * |
dc.author.google | Sarangi R. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.date.modifydate | 20240116111857 | * |