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Dodecanuclear rhenium cluster complexes with an interstitial carbon atom: Synthesis, structures and properties of two new compounds K6[Re 12CS17(OH)6]·4H2O and Na 12Re12CS17(SO3)6· 48.5H2O

Title
Dodecanuclear rhenium cluster complexes with an interstitial carbon atom: Synthesis, structures and properties of two new compounds K6[Re 12CS17(OH)6]·4H2O and Na 12Re12CS17(SO3)6· 48.5H2O
Authors
Mironov Y.V.Kozlova S.G.Kim S.-J.Sheldrick W.S.Fedorov V.E.
Ewha Authors
김성진
SCOPUS Author ID
김성진scopus
Issue Date
2010
Journal Title
Polyhedron
ISSN
0277-5387JCR Link
Citation
vol. 29, no. 18, pp. 3283 - 3286
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The dodecanuclear rhenium anionic complex with terminal hydroxo ligands [Re12CS17(OH)6]6- was obtained by the reaction of K6[Re12CS17(CN) 6]·20H2O with molten KOH at 300 °C. The cluster complex was crystallized as a potassium salt from aqueous solution. The reaction between K6[Re12CS17(OH) 6]·4H2O and Na2S2O 4 in water under reflux results in the formation of the complex Na12[Re12CS17(SO3) 6]·48.5H2O. Both new compounds were characterized by single-crystal X-ray diffraction, elemental analyses and IR spectroscopy. The electronic structure of [Re12CS17(OH)6] 6- was also elucidated by DFT calculations. © 2010 Elsevier B.V. All rights reserved.
DOI
10.1016/j.poly.2010.09.010
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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