Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김성진 | * |
dc.date.accessioned | 2016-08-28T12:08:56Z | - |
dc.date.available | 2016-08-28T12:08:56Z | - |
dc.date.issued | 2010 | * |
dc.identifier.issn | 0277-5387 | * |
dc.identifier.other | OAK-7165 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/221255 | - |
dc.description.abstract | The dodecanuclear rhenium anionic complex with terminal hydroxo ligands [Re12CS17(OH)6]6- was obtained by the reaction of K6[Re12CS17(CN) 6]·20H2O with molten KOH at 300 °C. The cluster complex was crystallized as a potassium salt from aqueous solution. The reaction between K6[Re12CS17(OH) 6]·4H2O and Na2S2O 4 in water under reflux results in the formation of the complex Na12[Re12CS17(SO3) 6]·48.5H2O. Both new compounds were characterized by single-crystal X-ray diffraction, elemental analyses and IR spectroscopy. The electronic structure of [Re12CS17(OH)6] 6- was also elucidated by DFT calculations. © 2010 Elsevier B.V. All rights reserved. | * |
dc.language | English | * |
dc.title | Dodecanuclear rhenium cluster complexes with an interstitial carbon atom: Synthesis, structures and properties of two new compounds K6[Re 12CS17(OH)6]·4H2O and Na 12Re12CS17(SO3)6· 48.5H2O | * |
dc.type | Article | * |
dc.relation.issue | 18 | * |
dc.relation.volume | 29 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 3283 | * |
dc.relation.lastpage | 3286 | * |
dc.relation.journaltitle | Polyhedron | * |
dc.identifier.doi | 10.1016/j.poly.2010.09.010 | * |
dc.identifier.wosid | WOS:000285531200003 | * |
dc.identifier.scopusid | 2-s2.0-78649332326 | * |
dc.author.google | Mironov Y.V. | * |
dc.author.google | Kozlova S.G. | * |
dc.author.google | Kim S.-J. | * |
dc.author.google | Sheldrick W.S. | * |
dc.author.google | Fedorov V.E. | * |
dc.contributor.scopusid | 김성진(56812714700) | * |
dc.date.modifydate | 20240301081003 | * |