Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 강원 | * |
dc.date.accessioned | 2016-08-28T11:08:04Z | - |
dc.date.available | 2016-08-28T11:08:04Z | - |
dc.date.issued | 2002 | * |
dc.identifier.issn | 1058-725X | * |
dc.identifier.other | OAK-1170 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/219050 | - |
dc.description.abstract | Single crystals of new organic metal, (ET)MT)2(BF 4)(THF). were electrochemically grown in an H-type cell. In the X-ray crystal structure, ET and MT donors together form a layer in ac-plane, which is stacking along b-axis alternatively with the layer formed by BF 4 - and THF. Within the mixed-donor layer, MT molecules (stacking along a-axis) and ET molecules (arranged side-by-side) are almost perpendicular each other with their long in-plane molecular axes being along b-axis. ET and MT molecules within a layer are closely connected by short S . . . S interactions (3.226-3.694 Å) and achieve the2D S . . . S network. Band electronic structure calculations on this complex show that it is a 2D metal at r.t. Bands are more dispersive along the a-axis which means that electrical conductivity is possibly better along this direction. However, the Fermi surface nesting which arises in many low dimensional metals, was not found. | * |
dc.language | English | * |
dc.title | New organic metal containing mixed donors: (ET)(MT)2(BF 4)(THF) | * |
dc.type | Conference Paper | * |
dc.relation.volume | 380 | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 123 | * |
dc.relation.lastpage | 128 | * |
dc.relation.journaltitle | Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals | * |
dc.identifier.doi | 10.1080/10587250290101450 | * |
dc.identifier.wosid | WOS:000177784900017 | * |
dc.identifier.scopusid | 2-s2.0-11144234262 | * |
dc.author.google | Noh D.-Y. | * |
dc.author.google | Han S.-W. | * |
dc.author.google | Lee H.-J. | * |
dc.author.google | Jung D. | * |
dc.author.google | Kang W. | * |
dc.contributor.scopusid | 강원(7202402145) | * |
dc.date.modifydate | 20240116110212 | * |