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A Manganese Compound I Model with a High Reactivity in the Oxidation of Organic Substrates and Water
- Title
- A Manganese Compound I Model with a High Reactivity in the Oxidation of Organic Substrates and Water
- Authors
- Zhang, Lina; Seo, Mi Sook; Choi, Yunhee; Ezhov, Roman; Maximova, Olga; Malik, Deesha D.; Ng, Maggie; Lee, Yong-Min; Sarangi, Ritimukta; Pushkar, Yulia N.; Cho, Kyung-Bin; Nam, Wonwoo
- Ewha Authors
- 남원우; 이용민; 서미숙
- SCOPUS Author ID
- 남원우; 이용민; 서미숙
- Issue Date
- 2023
- Journal Title
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- ISSN
- 0002-7863
1520-5126
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY vol. 145, no. 15, pp. 8319 - 8325
- Publisher
- AMER CHEMICAL SOC
- Indexed
- SCIE; SCOPUS
- Document Type
- Article
- Abstract
- A high-valent manganese(IV)-hydroxo porphyrin pi-cation radical complex, [Mn(IV)(OH)(Porp+center dot)(X)]+, was synthesized and characterized spectroscopically. The Mn porphyrin intermediate was highly reactive in alkane hydroxylation and oxygen atom transfer reactions. More importantly, the Mn porphyrin intermediate reacted with water at a fast rate, resulting in the dioxygen evolution. To the best of our knowledge, we report the first manganese Cpd I model compound bearing a porphyrin pi cation radical ligand with a high reactivity in oxidation reactions, including water oxidation.
- DOI
- 10.1021/jacs.3c01818|http://dx.doi.org/10.1021/jacs.3c01818
- Appears in Collections:
- 자연과학대학 > 화학·나노과학전공 > Journal papers
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