Full metadata record
DC Field | Value | Language |
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dc.contributor.author | 남원우 | * |
dc.contributor.author | 이용민 | * |
dc.date.accessioned | 2023-01-06T16:31:07Z | - |
dc.date.available | 2023-01-06T16:31:07Z | - |
dc.date.issued | 2023 | * |
dc.identifier.issn | 0010-8545 | * |
dc.identifier.issn | 1873-3840 | * |
dc.identifier.other | OAK-32747 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/263114 | - |
dc.description.abstract | The development of selective catalytic oxidation systems for alkene cis-dihydroxylation under environ-mentally benign conditions is an important goal that has long been pursued in the fields of synthetic and biomimetic chemistry and catalysis. Excellent examples for cis-dihydroxylation of alkenes are natu-rally occurring nonheme iron-dependent Rieske dioxygenases capable of performing aerobic regio-and stereoselective cis-dihydroxylation that is involved in the degradation of aromatics, with both oxygen atoms of O2 incorporated into the cis-dihydrodiol product. Inspired by the structural features of the non-heme iron enzyme center and the reaction mechanisms that underlie their efficacy to catalyze cis- dihydroxylation utilizing O2 and NADH as co-substrates, numerous nonheme iron complexes have been designed as the functional models of Rieske dioxygenases and demonstrated that those nonheme iron models catalyze the cis-dihydroxylation of alkenes with H2O2 as a terminal oxidant, yielding the cis- dihydrodiol products selectively. In this review, we describe recent developments of biologically inspired nonheme iron complexes for cis-dihydroxylation catalysis together with the evolution of the postulated reaction mechanisms to rationalize the experimental observations and the dichotomy between alkene cis-dihydroxylation and epoxidation, with particular emphasis on the structure-reactivity correlation of catalysts. These studies would provide important insights into the fundamental reaction pathways in enzymatic reactions and contribute to the rational design of efficient and selective bioinspired cis- dihydroxylation catalysts. (c) 2022 Published by Elsevier B.V. | * |
dc.language | English | * |
dc.publisher | ELSEVIER SCIENCE SA | * |
dc.subject | cis-Dihydroxylation | * |
dc.subject | Bioinspired catalysis | * |
dc.subject | Nonheme iron catalysts | * |
dc.subject | Rieske dioxygenases | * |
dc.subject | Mechanism | * |
dc.title | Biologically inspired nonheme iron complex-catalyzed cis-dihydroxylation of alkenes modeling Rieske dioxygenases | * |
dc.type | Review | * |
dc.relation.volume | 477 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.journaltitle | COORDINATION CHEMISTRY REVIEWS | * |
dc.identifier.doi | 10.1016/j.ccr.2022.214945 | * |
dc.identifier.wosid | WOS:000903751500001 | * |
dc.identifier.scopusid | 2-s2.0-85142745608 | * |
dc.author.google | Chen, Jie | * |
dc.author.google | Song, Wenxun | * |
dc.author.google | Lee, Yong-Min | * |
dc.author.google | Nam, Wonwoo | * |
dc.author.google | Wang, Bin | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.date.modifydate | 20240426135715 | * |