Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김영미 | * |
dc.date.accessioned | 2022-06-02T16:31:02Z | - |
dc.date.available | 2022-06-02T16:31:02Z | - |
dc.date.issued | 2022 | * |
dc.identifier.issn | 2046-2069 | * |
dc.identifier.other | OAK-31475 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/261188 | - |
dc.description.abstract | The diethylammonium counter-cations of the [Et2NH2]3[In3(BTB)4] metal-organic framework (InBTB MOF, BTB = 1,3,5-benzenetribenzoate) with an anionic framework can be effectively exchanged with cationic trans-[Co(en)2Cl2]+ complex ions through a simple cation-exchange process. The heterogenized trans-[Co(en)2Cl2]+-encapsulated InBTB MOF (trans-[Co(en)2Cl2]@InBTB) catalytic system maintained the activity of the captured trans-[Co(en)2Cl2]+ complex ion for hydrogen peroxide decomposition in aqueous solution under mild reaction conditions. The captured trans-[Co(en)2Cl2]+ complex also exhibited trans-cis isomerization to produce either cis-[Co(en)2Cl2]@InBTB or cis-[Co(en)2(H2O)Cl]@InBTB based on IR spectroscopic investigation. The trans-[Co(en)2Cl2]@InBTB catalytic system showed high recyclability for oxygen evolution from hydrogen peroxide. The catalytic ability of trans-[Co(en)2Cl2]@InBTB was maintained up to seven times of recycling. © 2022 The Royal Society of Chemistry | * |
dc.language | English | * |
dc.publisher | Royal Society of Chemistry | * |
dc.title | Catalytic oxygen evolution from hydrogen peroxide by trans-[Co(en)2Cl2]@InBTB metal-organic framework catalytic system | * |
dc.type | Article | * |
dc.relation.issue | 23 | * |
dc.relation.volume | 12 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 14450 | * |
dc.relation.lastpage | 14455 | * |
dc.relation.journaltitle | RSC Advances | * |
dc.identifier.doi | 10.1039/d2ra02208g | * |
dc.identifier.wosid | WOS:000793900200001 | * |
dc.identifier.scopusid | 2-s2.0-85131694300 | * |
dc.author.google | Yoon S. | * |
dc.author.google | Choi I.-H. | * |
dc.author.google | Kim Y. | * |
dc.author.google | Huh S. | * |
dc.contributor.scopusid | 김영미(57207443602) | * |
dc.date.modifydate | 20240301081003 | * |