Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김성진 | * |
dc.date.accessioned | 2021-08-12T16:32:26Z | - |
dc.date.available | 2021-08-12T16:32:26Z | - |
dc.date.issued | 2021 | * |
dc.identifier.issn | 2046-2069 | * |
dc.identifier.other | OAK-29866 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/258801 | - |
dc.description.abstract | A novel one-dimensional (1D) hybrid {[Re6S8(PzH)(6)][Pb3I8(DMF)(2)]}center dot 6(DMF) with hexarhenium cluster cations has been synthesized and characterized by means of single-crystal X-ray diffraction. Two DMF oxygen atoms bridge three lead iodides to form a set of lead iodides, {[PbI4/2I(O-DMF)(1/2)][PbI4/2(O-DMF)(2/2)][PbI4/2I(O-DMF)(1/2)]}(2-), and these sets of lead iodide share edges to form a 1D lead iodide chain, [Pb3I8(DMF)(2)](2-) which has never been reported before and is different from the typical edge sharing of octahedral PbI6 units. 1D lead iodide chains are stacked along the a axis, and [Re6S8(PzH)(6)](2+) cations with H-bonded DMF molecules to pyrazole N-H reside between 1D lead iodide chains. This 1D lead iodide hybrid shows strong broad-band emission with a peak at 634 nm. The excellent photoluminescent properties of the new lead iodide hybrid exhibit great potential for optoelectronic applications in photonic devices with broad-band emission and stability. This study introduces a new class of lead iodide hybrid compounds having new inorganic cluster cations rather than the organic amine cations that have been used in numerous studies to date. This work opens a promising path to overcome the instability of perovskites including of organic amine cations. | * |
dc.language | English | * |
dc.publisher | ROYAL SOC CHEMISTRY | * |
dc.title | One-dimensional lead iodide hybrid stabilized by inorganic hexarhenium cluster cations as a new broad-band emitter | * |
dc.type | Article | * |
dc.relation.issue | 40 | * |
dc.relation.volume | 11 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 24580 | * |
dc.relation.lastpage | 24587 | * |
dc.relation.journaltitle | RSC ADVANCES | * |
dc.identifier.doi | 10.1039/d1ra04170c | * |
dc.identifier.wosid | WOS:000678299000012 | * |
dc.identifier.scopusid | 2-s2.0-85111152573 | * |
dc.author.google | Ly, Giang Thi | * |
dc.author.google | Choi, Jun | * |
dc.author.google | Kim, Youngmee | * |
dc.author.google | Kim, Yuna | * |
dc.author.google | Kim, Sujin | * |
dc.author.google | Yang, So-Hyeon | * |
dc.author.google | Kim, Sung-Jin | * |
dc.contributor.scopusid | 김성진(56812714700) | * |
dc.date.modifydate | 20240301081003 | * |