Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 이용민 | * |
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | 서미숙 | * |
dc.date.accessioned | 2021-08-12T16:32:07Z | - |
dc.date.available | 2021-08-12T16:32:07Z | - |
dc.date.issued | 2020 | * |
dc.identifier.issn | 1433-7851 | * |
dc.identifier.issn | 1521-3773 | * |
dc.identifier.other | OAK-27252 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/258728 | - |
dc.description.abstract | A mononuclear nonheme cobalt(III) iodosylbenzene complex, [Co-III(TQA)(OIPh)(OH)](2+) (1), is synthesized and characterized structurally and spectroscopically. While 1 is a sluggish oxidant in oxidation reactions, it becomes a competent oxidant in oxygen atom transfer reactions, such as olefin epoxidation, in the presence of a small amount of proton. More interestingly, 1 shows a nucleophilic reactivity in aldehyde deformylation reaction, demonstrating that 1 has an amphoteric reactivity. Another interesting observation is that 1 can be used as an oxygen atom donor in the generation of high-valent metal-oxo complexes. To our knowledge, we present the first crystal structure of a Co-III iodosylbenzene complex and the unprecedented reactivity of metal-iodosylarene adduct. | * |
dc.language | English | * |
dc.publisher | WILEY-V C H VERLAG GMBH | * |
dc.subject | aldehyde deformylation reaction | * |
dc.subject | amphoteric reactivity | * |
dc.subject | cobalt(III) complexes | * |
dc.subject | iodosylbenzene adducts | * |
dc.subject | nonheme complexes | * |
dc.title | Structure and Unprecedented Reactivity of a Mononuclear Nonheme Cobalt(III) Iodosylbenzene Complex | * |
dc.type | Article | * |
dc.relation.issue | 32 | * |
dc.relation.volume | 59 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 13581 | * |
dc.relation.lastpage | 13585 | * |
dc.relation.journaltitle | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | * |
dc.identifier.doi | 10.1002/anie.202005091 | * |
dc.identifier.wosid | WOS:000535291000001 | * |
dc.identifier.scopusid | 2-s2.0-85085555773 | * |
dc.author.google | Yang, Jindou | * |
dc.author.google | Seo, Mi Sook | * |
dc.author.google | Kim, Kyung Ha | * |
dc.author.google | Lee, Yong-Min | * |
dc.author.google | Fukuzumi, Shunichi | * |
dc.author.google | Shearer, Jason | * |
dc.author.google | Nam, Wonwoo | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | 서미숙(7101805112) | * |
dc.date.modifydate | 20240802081000 | * |