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dc.contributor.author남원우*
dc.contributor.author이용민*
dc.contributor.authorShunichi Fukuzumi*
dc.contributor.author서미숙*
dc.date.accessioned2021-08-12T16:32:07Z-
dc.date.available2021-08-12T16:32:07Z-
dc.date.issued2020*
dc.identifier.issn1433-7851*
dc.identifier.issn1521-3773*
dc.identifier.otherOAK-27252*
dc.identifier.urihttps://dspace.ewha.ac.kr/handle/2015.oak/258728-
dc.description.abstractA mononuclear nonheme cobalt(III) iodosylbenzene complex, [Co-III(TQA)(OIPh)(OH)](2+) (1), is synthesized and characterized structurally and spectroscopically. While 1 is a sluggish oxidant in oxidation reactions, it becomes a competent oxidant in oxygen atom transfer reactions, such as olefin epoxidation, in the presence of a small amount of proton. More interestingly, 1 shows a nucleophilic reactivity in aldehyde deformylation reaction, demonstrating that 1 has an amphoteric reactivity. Another interesting observation is that 1 can be used as an oxygen atom donor in the generation of high-valent metal-oxo complexes. To our knowledge, we present the first crystal structure of a Co-III iodosylbenzene complex and the unprecedented reactivity of metal-iodosylarene adduct.*
dc.languageEnglish*
dc.publisherWILEY-V C H VERLAG GMBH*
dc.subjectaldehyde deformylation reaction*
dc.subjectamphoteric reactivity*
dc.subjectcobalt(III) complexes*
dc.subjectiodosylbenzene adducts*
dc.subjectnonheme complexes*
dc.titleStructure and Unprecedented Reactivity of a Mononuclear Nonheme Cobalt(III) Iodosylbenzene Complex*
dc.typeArticle*
dc.relation.issue32*
dc.relation.volume59*
dc.relation.indexSCIE*
dc.relation.indexSCOPUS*
dc.relation.startpage13581*
dc.relation.lastpage13585*
dc.relation.journaltitleANGEWANDTE CHEMIE-INTERNATIONAL EDITION*
dc.identifier.doi10.1002/anie.202005091*
dc.identifier.wosidWOS:000535291000001*
dc.identifier.scopusid2-s2.0-85085555773*
dc.author.googleYang, Jindou*
dc.author.googleSeo, Mi Sook*
dc.author.googleKim, Kyung Ha*
dc.author.googleLee, Yong-Min*
dc.author.googleFukuzumi, Shunichi*
dc.author.googleShearer, Jason*
dc.author.googleNam, Wonwoo*
dc.contributor.scopusid남원우(7006569723)*
dc.contributor.scopusidShunichi Fukuzumi(35430038100;58409757400)*
dc.contributor.scopusid서미숙(7101805112)*
dc.date.modifydate20240405124502*
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자연과학대학 > 화학·나노과학전공 > Journal papers
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