Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이상기 | * |
dc.contributor.author | 김현우 | * |
dc.date.accessioned | 2021-06-07T16:31:39Z | - |
dc.date.available | 2021-06-07T16:31:39Z | - |
dc.date.issued | 2021 | * |
dc.identifier.issn | 2041-6520 | * |
dc.identifier.other | OAK-29330 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/257660 | - |
dc.description.abstract | We have developed an electrochemically driven strategy for the stereoselective synthesis of protectedsyn-1,2-diols from vinylarenes withN,N-dimethylformamide (DMF). The newly developed system obviates the need for transition metal catalysts or external oxidizing agents, thus providing an operationally simple and efficient route to an array of protectedsyn-1,2-diols in a single step. This reaction proceedsviaan electrooxidation of olefin, followed by a nucleophilic attack of DMF. Subsequent oxidation and nucleophilic capture of the generated carbocation with a trifluoroacetate ion is proposed, which gives rise predominantly to asyn-diastereoselectivity upon the second nucleophilic attack of DMF. © The Royal Society of Chemistry 2021. | * |
dc.language | English | * |
dc.publisher | Royal Society of Chemistry | * |
dc.title | Electrochemically driven stereoselective approach tosyn-1,2-diol derivatives from vinylarenes and DMF | * |
dc.type | Article | * |
dc.relation.issue | 16 | * |
dc.relation.volume | 12 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 5892 | * |
dc.relation.lastpage | 5897 | * |
dc.relation.journaltitle | Chemical Science | * |
dc.identifier.doi | 10.1039/d1sc00760b | * |
dc.identifier.wosid | WOS:000632976600001 | * |
dc.identifier.scopusid | 2-s2.0-85105160663 | * |
dc.author.google | Chung D.S. | * |
dc.author.google | Park S.H. | * |
dc.author.google | Lee S.-G. | * |
dc.author.google | Kim H. | * |
dc.contributor.scopusid | 이상기(15082786300) | * |
dc.contributor.scopusid | 김현우(57214329410) | * |
dc.date.modifydate | 20240123104103 | * |