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Proton-promoted disproportionation of iron(V)-imido TAML to iron(V)-imido TAML cation radical and iron(IV) TAML

Title
Proton-promoted disproportionation of iron(V)-imido TAML to iron(V)-imido TAML cation radical and iron(IV) TAML
Authors
Lu X.Lee Y.-M.Seo M.S.Nam W.
Ewha Authors
남원우이용민서미숙
SCOPUS Author ID
남원우scopus; 이용민scopusscopus; 서미숙scopusscopus
Issue Date
2020
Journal Title
Chemical communications (Cambridge, England)
ISSN
1364-548XJCR Link
Citation
Chemical communications (Cambridge, England) vol. 56, no. 76, pp. 11207 - 11210
Publisher
NLM (Medline)
Indexed
SCOPUS scopus
Document Type
Article
Abstract
The present study reports the first example of a proton-promoted disproportionation reaction of a non-heme iron(v)-imido TAML (1) complex to give an iron(v)-imido TAML cation radical (2) and an iron(iv) TAML (3) upon addition of acids. Detailed mechanistic investigations revealed that two molecules of 1 react with one proton to yield 2 and [FeIV(NHTs)(TAML)]- (4), followed by the reaction of 4 with another proton to afford 3 and NH2Ts.
DOI
10.1039/d0cc05145d
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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