View : 89 Download: 0

Artificial nonheme iron and manganese oxygenases for enantioselective olefin epoxidation and alkane hydroxylation reactions

Title
Artificial nonheme iron and manganese oxygenases for enantioselective olefin epoxidation and alkane hydroxylation reactions
Authors
Chen, JieJiang, ZhankunFukuzumi, ShunichiNam, WonwooWang, Bin
Ewha Authors
남원우Shunichi Fukuzumi
SCOPUS Author ID
남원우scopus; Shunichi Fukuzumiscopus
Issue Date
2020
Journal Title
COORDINATION CHEMISTRY REVIEWS
ISSN
0010-8545JCR Link

1873-3840JCR Link
Citation
COORDINATION CHEMISTRY REVIEWS vol. 421
Keywords
Enantioselective epoxidation and hydroxylationBioinspired catalysisNonheme iron and manganese catalystsMechanism
Publisher
ELSEVIER SCIENCE SA
Indexed
SCIE; SCOPUS WOS scopus
Document Type
Review
Abstract
The development of sustainable enantioselective olefin epoxidation and alkane oxidation reactions under environmentally friendly conditions is an ultimate goal that has long been pursued in chemistry. Excellent examples are naturally occurring monooxygenases, which are able to catalyze a variety of biological oxidation reactions using molecular oxygen (O-2) that afford high chemo-, regio-, and/or stereo-selectivities. Inspired by the oxidation reactions of iron-containing monooxygenases, substantial efforts have been made towards the development of efficient catalysis for the enantioselective oxidation of hydrocarbons using bioinspired nonheme iron and manganese catalysts under mild conditions. In this review, we describe synthetic models that functionally mimic these monooxygenases. There are a large number of nonheme iron and manganese complexes that can epoxidize olefins with high enantioselectivities, whereas only a few examples are reported for nonheme iron- and manganese-catalyzed enantioselective oxidation of inert C(sp(3))-H bonds. In addition to its great achievement for synthetic applications, mechanistic studies in biomimetic oxidation systems have also been intensively investigated, providing important insights into the understanding of the nature of active oxidants and the formation of the intermediates via O-O bond activation and the design of more elegant biomimetic oxidation catalysts. Thus, these bioinspired nonheme iron and manganese complexes used as catalysts in the enantioselective C=C epoxidation and aliphatic C(sp(3))-H oxidation are the focus of discussion in this review. (C) 2020 Elsevier B.V. All rights reserved.
DOI
10.1016/j.ccr.2020.213443
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE