DSpace at EWHA: Asymmetric Total Syntheses of Kopsane Alkaloids via a PtCl2-Catalyzed Intramolecular [3+2] Cycloaddition

Browse

My Repository

View : 548 Download: 0

Full metadata record

DC Field	Value	Language
dc.contributor.author	최선	*
dc.date.accessioned	2020-08-13T16:30:07Z	-
dc.date.available	2020-08-13T16:30:07Z	-
dc.date.issued	2020	*
dc.identifier.issn	0044-8249	*
dc.identifier.other	OAK-27290	*
dc.identifier.uri	https://dspace.ewha.ac.kr/handle/2015.oak/254903	-
dc.description.abstract	A concise and asymmetric total synthesis of five kopsane alkaloids that share a unique heptacyclic caged ring system was accomplished. The key transformation in the sequence involved a remarkable PtCl2-catalyzed intramolecular [3+2] cycloaddition, which allowed for the rapid assembly of pentacyclic carbon skeletons bearing 2,3-quaternary functionalized indoline. Expeditious construction of diverse indoline scaffolds with excellent control of diastereoselectivity demonstrated the broad scope and versatility of this key transformation. © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim	*
dc.language	English	*
dc.publisher	Wiley-Blackwell	*
dc.subject	alkaloids	*
dc.subject	kopsanes	*
dc.subject	natural products	*
dc.subject	Pt catalysis	*
dc.subject	[3+2] cycloaddition reactions	*
dc.title	Asymmetric Total Syntheses of Kopsane Alkaloids via a PtCl2-Catalyzed Intramolecular [3+2] Cycloaddition	*
dc.type	Article	*
dc.relation.issue	31	*
dc.relation.volume	132	*
dc.relation.index	SCOPUS	*
dc.relation.startpage	12932	*
dc.relation.lastpage	12936	*
dc.relation.journaltitle	Angewandte Chemie	*
dc.identifier.doi	10.1002/ange.202005048	*
dc.identifier.scopusid	2-s2.0-85088382326	*
dc.author.google	Jia X.	*
dc.author.google	Lei H.	*
dc.author.google	Han F.	*
dc.author.google	Zhang T.	*
dc.author.google	Chen Y.	*
dc.author.google	Xu Z.	*
dc.author.google	Nakliang P.	*
dc.author.google	Choi S.	*
dc.author.google	Guo Y.	*
dc.author.google	Ye T.	*
dc.contributor.scopusid	최선(8659831000)	*
dc.date.modifydate	20240305081003	*