Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 이용민 | * |
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | 서미숙 | * |
dc.contributor.author | 김원석 | * |
dc.date.accessioned | 2019-12-03T16:30:36Z | - |
dc.date.available | 2019-12-03T16:30:36Z | - |
dc.date.issued | 2019 | * |
dc.identifier.issn | 1433-7851 | * |
dc.identifier.other | OAK-26133 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/252339 | - |
dc.description.abstract | A mononuclear nonheme manganese(IV)–oxo complex binding the Ce4+ ion, [(dpaq)MnIV(O)]+–Ce4+ (1-Ce4+), was synthesized by reacting [(dpaq)MnIII(OH)]+ (2) with cerium ammonium nitrate (CAN). 1-Ce4+ was characterized using various spectroscopic techniques, such as UV/Vis, EPR, CSI-MS, resonance Raman, XANES, and EXAFS, showing an Mn−O bond distance of 1.69 Å with a resonance Raman band at 675 cm−1. Electron-transfer and oxygen atom transfer reactivities of 1-Ce4+ were found to be greater than those of MnIV(O) intermediates binding redox-inactive metal ions (1-Mn+). This study reports the first example of a redox-active Ce4+ ion-bound MnIV-oxo complex and its spectroscopic characterization and chemical properties. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | * |
dc.language | English | * |
dc.publisher | Wiley-VCH Verlag | * |
dc.subject | biomimetic chemistry | * |
dc.subject | electron transfer | * |
dc.subject | high-valent manganese–oxo | * |
dc.subject | oxygen atom transfer | * |
dc.subject | redox-active metal ions | * |
dc.title | A High-Valent Manganese(IV)–Oxo–Cerium(IV) Complex and Its Enhanced Oxidizing Reactivity | * |
dc.type | Article | * |
dc.relation.issue | 45 | * |
dc.relation.volume | 58 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 16124 | * |
dc.relation.lastpage | 16129 | * |
dc.relation.journaltitle | Angewandte Chemie - International Edition | * |
dc.identifier.doi | 10.1002/anie.201910032 | * |
dc.identifier.scopusid | 2-s2.0-85074026420 | * |
dc.author.google | Karmalkar D.G. | * |
dc.author.google | Sankaralingam M. | * |
dc.author.google | Seo M.S. | * |
dc.author.google | Ezhov R. | * |
dc.author.google | Lee Y.-M. | * |
dc.author.google | Pushkar Y.N. | * |
dc.author.google | Kim W.-S. | * |
dc.author.google | Fukuzumi S. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | 서미숙(7101805112) | * |
dc.contributor.scopusid | 김원석(57203484044) | * |
dc.date.modifydate | 20240802081000 | * |