Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 서미숙 | * |
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | 이용민 | * |
dc.contributor.author | Mian Guo | * |
dc.date.accessioned | 2019-09-03T16:30:05Z | - |
dc.date.available | 2019-09-03T16:30:05Z | - |
dc.date.issued | 2019 | * |
dc.identifier.issn | 0002-7863 | * |
dc.identifier.issn | 1520-5126 | * |
dc.identifier.other | OAK-25315 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/251372 | - |
dc.description.abstract | We report that Mn(IV)-oxo porphyrin complexes, Mn-IV(O)(TMP) (1) and Mn-IV(O)(TDCPP) (2), are capable of activating the C-H bonds of hydrocarbons, including unactivated alkanes such as cyclohexane, via an oxygen non-rebound mechanism. Interestingly, 1 with an electron-rich porphyrin is more reactive than 2 with an electron-deficient porphyrin at a high temperature (e.g., 0 degrees C). However, at a low temperature (e.g., -40 degrees C), the reactivity of 1 and 2 is reversed, showing that 2 is more reactive than 1. To the best of our knowledge, the present study reports the first example of highly reactive Mn(IV)-oxo porphyrins and their temperature-dependent reactivity in C-H bond activation reactions. | * |
dc.language | English | * |
dc.publisher | AMER CHEMICAL SOC | * |
dc.title | Highly Reactive Manganese(IV)-Oxo Porphyrins Showing Temperature-Dependent Reversed Electronic Effect in C-H Bond Activation Reactions | * |
dc.type | Article | * |
dc.relation.issue | 31 | * |
dc.relation.volume | 141 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 12187 | * |
dc.relation.lastpage | 12191 | * |
dc.relation.journaltitle | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | * |
dc.identifier.doi | 10.1021/jacs.9b04496 | * |
dc.identifier.wosid | WOS:000480497100003 | * |
dc.identifier.scopusid | 2-s2.0-85070557933 | * |
dc.author.google | Guo, Mian | * |
dc.author.google | Seo, Mi Sook | * |
dc.author.google | Lee, Yong-Min | * |
dc.author.google | Fukuzumi, Shunichi | * |
dc.author.google | Nam, Wonwoo | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.contributor.scopusid | Mian Guo(57193833363) | * |
dc.date.modifydate | 20240426135715 | * |