Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | Shunichi Fukuzumi | * |
dc.date.accessioned | 2019-08-22T16:30:27Z | - |
dc.date.available | 2019-08-22T16:30:27Z | - |
dc.date.issued | 2019 | * |
dc.identifier.issn | 0020-1669 | * |
dc.identifier.issn | 1520-510X | * |
dc.identifier.other | OAK-25172 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/251275 | - |
dc.description.abstract | The electron-transfer (ET) processes from electron-donor substrates to oxoiron(IV) porphyrin pi-cation-radical species (Cpd I) are key steps in their oxygenation reactions. Here, we have evaluated the rate constants of the outer-sphere ET reduction of Cpd I model complexes of meso-tetramesitylporphyrin (1) and 2,7,12,17-tetramesity1-3,8,13,18-tetramethylporphyrin (2) in light of the Marcus theory of ET to determine the ET reorganization energies (lambda). The lambda values of the ligand-centered ET reduction of Cpd I model complexes are much smaller than those of the metal-centered ET reduction of various oxoiron(IV) complexes. Moreover, the lambda value of 1 is larger than that of 2, resulting from the difference in the nature of the a(1u)/a(2u) porphyrin pi-cation radical orbitals. | * |
dc.language | English | * |
dc.publisher | AMER CHEMICAL SOC | * |
dc.title | Small Reorganization Energy for Ligand-Centered Electron-Transfer Reduction of Compound I to Compound II in a Heme Model Study | * |
dc.type | Article | * |
dc.relation.issue | 13 | * |
dc.relation.volume | 58 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 8263 | * |
dc.relation.lastpage | 8266 | * |
dc.relation.journaltitle | INORGANIC CHEMISTRY | * |
dc.identifier.doi | 10.1021/acs.inorgchem.9b01051 | * |
dc.identifier.wosid | WOS:000474475800003 | * |
dc.author.google | Fukui, Nami | * |
dc.author.google | Li, Xiao-Xi | * |
dc.author.google | Nam, Wonwoo | * |
dc.author.google | Fukuzumi, Shunichi | * |
dc.author.google | Fujii, Hiroshi | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.date.modifydate | 20240401081001 | * |