Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이상기 | * |
dc.date.accessioned | 2019-01-24T16:30:16Z | - |
dc.date.available | 2019-01-24T16:30:16Z | - |
dc.date.issued | 2018 | * |
dc.identifier.issn | 1433-7851 | * |
dc.identifier.issn | 1521-3773 | * |
dc.identifier.other | OAK-24114 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/248267 | - |
dc.description.abstract | Reported is a tandem palladium-catalyzed Heck/regioselective C(sp(3))-H activation reaction for the divergent synthesis of spiro- and fused-cyclopropanated indolines from N-methallylated 2-bromoarylamides. The regioselectivity of the C-H bond activation in the s-alkylPdII intermediate is controlled by the solvent used. DFT calculations suggest that the polarity of solvent molecules could influence the transition-state energy, leading to a bifurcation of the C-H bond activation in the s-alkylPdII intermediate. | * |
dc.language | English | * |
dc.publisher | WILEY-V C H VERLAG GMBH | * |
dc.subject | C-H activation | * |
dc.subject | heterocylces | * |
dc.subject | palladium | * |
dc.subject | reaction mechanisms | * |
dc.subject | solvent effects | * |
dc.title | Palladium-Catalyzed Divergent Cyclopropanation by Regioselective Solvent-Driven C(sp(3))-H Bond Activation | * |
dc.type | Article | * |
dc.relation.issue | 47 | * |
dc.relation.volume | 57 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 15460 | * |
dc.relation.lastpage | 15464 | * |
dc.relation.journaltitle | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | * |
dc.identifier.doi | 10.1002/anie.201809133 | * |
dc.identifier.wosid | WOS:000453344500027 | * |
dc.author.google | Chung, Da Sol | * |
dc.author.google | Lee, Jae Sung | * |
dc.author.google | Ryu, Ho | * |
dc.author.google | Park, Jiyong | * |
dc.author.google | Kim, Hyunjoong | * |
dc.author.google | Lee, Joo Hyun | * |
dc.author.google | Kim, U. Bin | * |
dc.author.google | Lee, Won Koo | * |
dc.author.google | Baik, Mu-Hyun | * |
dc.author.google | Lee, Sang-gi | * |
dc.contributor.scopusid | 이상기(15082786300) | * |
dc.date.modifydate | 20240123104103 | * |