Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | 이용민 | * |
dc.date.accessioned | 2019-01-02T16:30:15Z | - |
dc.date.available | 2019-01-02T16:30:15Z | - |
dc.date.issued | 2018 | * |
dc.identifier.issn | 1477-9226 | * |
dc.identifier.issn | 1477-9234 | * |
dc.identifier.other | OAK-24027 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/248070 | - |
dc.description.abstract | Recent advances on the excited state chemistry of metal-oxygen synthetic complexes based on earth-abundant metals such as copper, cobalt, and manganese are reviewed to show a much enhanced reactivity of the photoexcited states as compared with their relative ground states. Mononuclear copper(II)-superoxide and dinuclear copper(II)-peroxo complexes underwent copper-oxygen bond cleavage, dioxygen release, and copper(I)/dioxygen rebinding upon photoexcitation at low temperature. Photoirradiation of the cobalt-oxygen compound [(TAML)Co-IV(O)](2-) (6) (TAML = tetraamidomacrocyclic ligand) at 5 degrees C yielded a cobalt-oxygen excited state with 0.6(1) ns lifetime, showing a high reactivity in the bimolecular electron-transfer oxidations of m-xylene and anisole. An extremely long-lived excited state was generated upon photoexcitation of a manganese(IV)-oxo complex binding two Sc(OTf)(3) molecules, which enabled the hydroxylation of benzene. | * |
dc.language | English | * |
dc.publisher | ROYAL SOC CHEMISTRY | * |
dc.title | Photoexcited state chemistry of metal-oxygen complexes | * |
dc.type | Review | * |
dc.relation.issue | 45 | * |
dc.relation.volume | 47 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 16019 | * |
dc.relation.lastpage | 16026 | * |
dc.relation.journaltitle | DALTON TRANSACTIONS | * |
dc.identifier.doi | 10.1039/c8dt03604g | * |
dc.identifier.wosid | WOS:000451018400002 | * |
dc.author.google | Saracini, Claudio | * |
dc.author.google | Fukuzumi, Shunichi | * |
dc.author.google | Lee, Yong-Min | * |
dc.author.google | Nam, Wonwoo | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.date.modifydate | 20240802081000 | * |