Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 서미숙 | * |
dc.date.accessioned | 2019-01-02T16:30:04Z | - |
dc.date.available | 2019-01-02T16:30:04Z | - |
dc.date.issued | 2018 | * |
dc.identifier.issn | 0947-6539 | * |
dc.identifier.other | OAK-24097 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/248013 | - |
dc.description.abstract | A mononuclear manganese(V)–oxo complex with tetraamido macrocyclic ligand (TAML), [MnV(O)(TAML)]− (1), is a sluggish oxidant in oxidation reactions. Herein, a mononuclear manganese(V)–oxo TAML cation radical complex, [MnV(O)(TAML+.)] (2), is reported. It was synthesized by reacting [MnIII(TAML)]− with 3.0 equivalents of [RuIII(bpy)3]3+ or upon addition of one-electron oxidant to 1 and then characterized thoroughly with various spectroscopic techniques along with DFT calculations. Although 1 is a sluggish oxidant, 2 is a strong oxidant capable of activating C−H bonds of hydrocarbons (i.e., hydrogen atom transfer reaction) and transferring its oxygen atom to thioanisoles and olefins (i.e., oxygen atom transfer reaction). © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | * |
dc.language | English | * |
dc.publisher | Wiley-VCH Verlag | * |
dc.subject | C−H bond activation | * |
dc.subject | manganese | * |
dc.subject | olefin epoxidation | * |
dc.subject | radicals | * |
dc.subject | sulfoxidation | * |
dc.title | A Manganese(V)–Oxo Tetraamido Macrocyclic Ligand (TAML) Cation Radical Complex: Synthesis, Characterization, and Reactivity Studies | * |
dc.type | Article | * |
dc.relation.issue | 68 | * |
dc.relation.volume | 24 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 17927 | * |
dc.relation.lastpage | 17931 | * |
dc.relation.journaltitle | Chemistry - A European Journal | * |
dc.identifier.doi | 10.1002/chem.201804898 | * |
dc.identifier.wosid | WOS:000453050900010 | * |
dc.identifier.scopusid | 2-s2.0-85056708710 | * |
dc.author.google | Karmalkar D.G. | * |
dc.author.google | Li X.-X. | * |
dc.author.google | Seo M.S. | * |
dc.author.google | Sankaralingam M. | * |
dc.author.google | Ohta T. | * |
dc.author.google | Sarangi R. | * |
dc.author.google | Hong S. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | 서미숙(7101805112) | * |
dc.date.modifydate | 20240405124941 | * |