Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | Shunichi Fukuzumi | * |
dc.date.accessioned | 2018-12-14T16:30:47Z | - |
dc.date.available | 2018-12-14T16:30:47Z | - |
dc.date.issued | 2018 | * |
dc.identifier.issn | 0002-7863 | * |
dc.identifier.other | OAK-22679 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/247699 | - |
dc.description.abstract | Photoexcitation of a MnIV-oxo complex binding scandium ions ([(Bn-TPEN)MnIV(O)]2+-(Sc(OTf)3)2) in a solvent mixture of trifluoroethanol and acetonitrile (v/v = 1:1) resulted in formation of the long-lived photoexcited state, which can hydroxylate benzene to phenol. The photohydroxylation of benzene by [(Bn-TPEN)MnIV(O)]2+-(Sc(OTf)3)2 was made possible by electron transfer from benzene to the long-lived 2E excited state of [(Bn-TPEN)MnIV(O)]2+-(Sc(OTf)3)2 to produce a benzene radical cation, which reacted with water as revealed by laser-induced transient absorption measurements. © 2018 American Chemical Society. | * |
dc.language | English | * |
dc.publisher | American Chemical Society | * |
dc.title | Long-Lived Photoexcited State of a Mn(IV)-Oxo Complex Binding Scandium Ions That is Capable of Hydroxylating Benzene | * |
dc.type | Article | * |
dc.relation.issue | 27 | * |
dc.relation.volume | 140 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 8405 | * |
dc.relation.lastpage | 8409 | * |
dc.relation.journaltitle | Journal of the American Chemical Society | * |
dc.identifier.doi | 10.1021/jacs.8b04904 | * |
dc.identifier.wosid | WOS:000439009200010 | * |
dc.identifier.scopusid | 2-s2.0-85048823513 | * |
dc.author.google | Sharma N. | * |
dc.author.google | Jung J. | * |
dc.author.google | Ohkubo K. | * |
dc.author.google | Lee Y.-M. | * |
dc.author.google | El-Khouly M.E. | * |
dc.author.google | Nam W. | * |
dc.author.google | Fukuzumi S. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.date.modifydate | 20240802081000 | * |