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dc.contributor.author김영미-
dc.contributor.authorJean Bouffard-
dc.date.accessioned2018-12-14T16:30:23Z-
dc.date.available2018-12-14T16:30:23Z-
dc.date.issued2018-
dc.identifier.issn0022-3263-
dc.identifier.otherOAK-22893-
dc.identifier.urihttp://dspace.ewha.ac.kr/handle/2015.oak/247567-
dc.description.abstractDespite the common use of quinones as oxidizing agents in N-heterocyclic carbene (NHC)-based organocatalysis and transition-metal catalysis, the direct reactivity of quinones with NHCs remains underexplored. In this paper, we report the reactivity of NHCs with common p- and o-quinones, uncovering three unreported reactions involving contractions of the quinone ring that lead to push pull furanolactone chromophores, NHC fulvalenes, and a-acylimidazolium cyclopentenone derivatives. These experiments also provide a rationale for the superior compatibility of tetra-tert-alkylated diphenoquinones in NHC-based oxidative transformations.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.titleAddition, Substitution, and Ring-Contraction Reactions of Quinones with N-Heterocyclic Carbenes-
dc.typeArticle-
dc.relation.issue16-
dc.relation.volume83-
dc.relation.indexSCI-
dc.relation.indexSCIE-
dc.relation.indexSCOPUS-
dc.relation.startpage9240-
dc.relation.lastpage9249-
dc.relation.journaltitleJOURNAL OF ORGANIC CHEMISTRY-
dc.identifier.doi10.1021/acs.joc.8b01236-
dc.identifier.wosidWOS:000442451500031-
dc.identifier.scopusid2-s2.0-85051747992-
dc.author.googlePing, Lucy-
dc.author.googleBak, JungMin-
dc.author.googleKim, Youngmee-
dc.author.googleBouffard, Jean-
dc.contributor.scopusid김영미(8361744900)-
dc.contributor.scopusidJean Bouffard(8892273200)-
dc.date.modifydate20181231112831-
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자연과학대학 > 화학·나노과학전공 > Journal papers
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