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자연과학대학
화학·나노과학전공
Journal papers
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Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect
Title
Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect
Authors
Derrick J.S.
;
Kim Y.
;
Tak H.
;
Park K.
;
Cho J.
;
Kim S.H.
;
Lim M.H.
Ewha Authors
김선희
SCOPUS Author ID
김선희
Issue Date
2017
Journal Title
Dalton Transactions
ISSN
1477-9226
Citation
Dalton Transactions vol. 46, no. 39, pp. 13166 - 13170
Publisher
Royal Society of Chemistry
Indexed
SCIE; SCOPUS
Document Type
Article
Abstract
Metal(TMC) complexes (TMC = tetramethylcyclam) exclusively form trans-I diastereoisomers; thus, little is known about the trans-III isomers. Herein, we report a new method to prepare the trans-III-[Cu(TMC)]2+ complex via an anion effect. Our crystallographic, spectroscopic, and computational analyses validated that [Cu(TMC)](NO3)2 produced the trans-III complex, different from the trans-I structure of [Cu(TMC)](ClO4)2. © 2017 The Royal Society of Chemistry.
DOI
10.1039/c7dt01489a
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