Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 이용민 | * |
dc.date.accessioned | 2018-11-16T16:30:11Z | - |
dc.date.available | 2018-11-16T16:30:11Z | - |
dc.date.issued | 2018 | * |
dc.identifier.issn | 2041-6520 | * |
dc.identifier.issn | 2041-6539 | * |
dc.identifier.other | OAK-23480 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/246570 | - |
dc.description.abstract | While the synthesis and characterization of {FeNO}(7,8,9) complexes have been well documented in heme and nonheme iron models, {FeNO}(6) complexes have been less clearly understood. Herein, we report the synthesis and structural and spectroscopic characterization of mononuclear nonheme {FeNO}(6) and iron(iii)-nitrito complexes bearing a tetraamido macrocyclic ligand (TAML), such as [(TAML)Fe-III(NO)](-) and [(TAML)Fe-III(NO2)](2-), respectively. First, direct addition of NO(g) to [Fe-III(TAML)](-) results in the formation of [(TAML)Fe-III(NO)](-), which is sensitive to moisture and air. The spectroscopic data of [(TAML)Fe-III(NO)](-), such as H-1 nuclear magnetic resonance and X-ray absorption spectroscopies, combined with computational study suggest the neutral nature of nitric oxide with a diamagnetic Fe center (S = 0). We also provide alternative pathways for the generation of [(TAML)Fe-III(NO)](-), such as the iron-nitrite reduction triggered by protonation in the presence of ferrocene, which acts as an electron donor, and the photochemical iron-nitrite reduction. To the best of our knowledge, the present study reports the first photochemical nitrite reduction in nonheme iron models. | * |
dc.language | English | * |
dc.publisher | ROYAL SOC CHEMISTRY | * |
dc.title | A mononuclear nonheme {FeNO}(6) complex: synthesis and structural and spectroscopic characterization | * |
dc.type | Article | * |
dc.relation.issue | 34 | * |
dc.relation.volume | 9 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 6952 | * |
dc.relation.lastpage | 6960 | * |
dc.relation.journaltitle | CHEMICAL SCIENCE | * |
dc.identifier.doi | 10.1039/c8sc01962b | * |
dc.identifier.wosid | WOS:000444554100009 | * |
dc.identifier.scopusid | 2-s2.0-85052749128 | * |
dc.author.google | Hong, Seungwoo | * |
dc.author.google | Yan, James J. | * |
dc.author.google | Karmalkar, Deepika G. | * |
dc.author.google | Sutherlin, Kyle D. | * |
dc.author.google | Kim, Jin | * |
dc.author.google | Lee, Yong-Min | * |
dc.author.google | Goo, Yire | * |
dc.author.google | Mascharak, Pradip K. | * |
dc.author.google | Hedman, Britt | * |
dc.author.google | Hodgson, Keith O. | * |
dc.author.google | Karlin, Kenneth D. | * |
dc.author.google | Solomon, Edward I. | * |
dc.author.google | Nam, Wonwoo | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.date.modifydate | 20240426135715 | * |