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The effect of solvent on the α-effect: C=O, P=O and SO2 centers

Title
The effect of solvent on the α-effect: C=O, P=O and SO2 centers
Authors
Um I.-H.Hong J.-Y.Buncel E.
Ewha Authors
엄익환
SCOPUS Author ID
엄익환scopusscopus
Issue Date
2001
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
no. 1, pp. 27 - 28
Indexed
SCI; SCIE; SCOPUS scopus
Abstract
The α-effect for the reaction of a sulfonyl ester exhibits a bell-shaped dependence of the α-effect on solvent composition as do the corresponding reactions with a carbonyl and a phosphinyl ester, and the magnitude of the α-effect is found to be dependent on the magnitude of the βnuc value, suggesting TS stabilization as the cause of the α-effect.
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자연과학대학 > 화학·나노과학전공 > Journal papers
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