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Significant and differential acceleration of dephosphorylation of the insecticides, paraoxon and parathion, caused by alkali metal ethoxides

Title
Significant and differential acceleration of dephosphorylation of the insecticides, paraoxon and parathion, caused by alkali metal ethoxides
Authors
Um I.-H.Jeon S.-E.Baek M.-H.Park H.-R.
Ewha Authors
엄익환
SCOPUS Author ID
엄익환scopusscopus
Issue Date
2003
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
vol. 9, no. 24, pp. 3016 - 3017
Indexed
SCI; SCIE; SCOPUS scopus
Abstract
In the reaction of paraoxon with alkali metal ethoxides, ion-paired EtO -M + species are more reactive than the dissociated EtO - with the reactivity order EtO -Li + > EtO -Na + > EtO -K + > EtO -, while in the reaction of parathion, the reactivity follows the order EtO -K + > EtO - > EtO -Na + > EtO -Li +.
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자연과학대학 > 화학·나노과학전공 > Journal papers
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