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Glycerol as ligand: The synthesis, crystal structure, and properties of compounds [Ln2(H2L)2(H3L) 4][Re6Q8(CN)6], Ln = La, Nd, Gd, Q = S, Se

Title
Glycerol as ligand: The synthesis, crystal structure, and properties of compounds [Ln2(H2L)2(H3L) 4][Re6Q8(CN)6], Ln = La, Nd, Gd, Q = S, Se
Authors
Naumov N.G.Tarasenko M.S.Virovets A.V.Kim Y.Kim S.-J.Fedorov V.E.
Ewha Authors
김성진김영미
SCOPUS Author ID
김성진scopus; 김영미scopus
Issue Date
2006
Journal Title
European Journal of Inorganic Chemistry
ISSN
1434-1948JCR Link
Citation
European Journal of Inorganic Chemistry, no. 2, pp. 298 - 303
Indexed
SCI; SCIE; SCOPUS WOS scopus
Document Type
Article
Abstract
The interaction of aqueous solutions of octahedral cluster anions [Re 6Q8(CN)6]4- with rare earth cations in the presence of glycerol resulted in the formation of a new family of compounds [Ln2(H2L)2(H3L) 4][Re6Q8(CN)6] (where Ln = La, Nd, and Gd; Q = S, Se; H3L = glycerol; H2L- = glycerolate anion). All compounds are isostructural and crystallize in the P1 space group. Crystal structures are built from octahedral cluster anions [Re6Q8(CN)6]4- and centrosymmetrical dimers [Ln2(H2L)2(H3L) 4]4+ that have three different binding modes of glycerol. © Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
DOI
10.1002/ejic.200500542
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자연과학대학 > 화학·나노과학전공 > Journal papers
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