Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.date.accessioned | 2018-05-30T08:13:57Z | - |
dc.date.available | 2018-05-30T08:13:57Z | - |
dc.date.issued | 2006 | * |
dc.identifier.issn | 0162-0134 | * |
dc.identifier.other | OAK-3349 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/243452 | - |
dc.description.abstract | The push effect of anionic axial ligands of high-valent iron(IV)-oxo porphyrin π-cation radicals, (Porp)+{radical dot}FeIV(O)(X) (X = OH-, AcO-, Cl-, and CF3 SO3-), in alkane hydroxylation is investigated by B3LYP DFT calculations. The electron-donating ability of anionic axial ligands influences the activation energy for the alkane hydroxylation by the iron(IV)-oxo intermediates and the Fe-O bond distance of the iron-oxo species in transition state. © 2006 Elsevier Inc. All rights reserved. | * |
dc.language | English | * |
dc.title | How axial ligands control the reactivity of high-valent iron(IV)-oxo porphyrin π-cation radicals in alkane hydroxylation: A computational study | * |
dc.type | Article | * |
dc.relation.issue | 4 | * |
dc.relation.volume | 100 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 751 | * |
dc.relation.lastpage | 754 | * |
dc.relation.journaltitle | Journal of Inorganic Biochemistry | * |
dc.identifier.doi | 10.1016/j.jinorgbio.2006.01.007 | * |
dc.identifier.wosid | WOS:000237829000030 | * |
dc.identifier.scopusid | 2-s2.0-33645882537 | * |
dc.author.google | Kamachi T. | * |
dc.author.google | Kouno T. | * |
dc.author.google | Nam W. | * |
dc.author.google | Yoshizawa K. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.date.modifydate | 20240116111857 | * |