Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 최진호 | - |
dc.date.accessioned | 2018-05-18T08:15:01Z | - |
dc.date.available | 2018-05-18T08:15:01Z | - |
dc.date.issued | 2005 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.other | OAK-2786 | - |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/243107 | - |
dc.description.abstract | A novel lamellar inorganic-inorganic nanohybrid (TiO2-pillared MoS2) has been successfully synthesized by an exfoliation- reassembling method. According to the X-ray diffraction and cross-sectional transmission electron microscopy analyses, quantum-sized TiO2 nanoparticles with a diameter of 1 nm are homogeneously distributed in the interlayer space of a two-dimensional MoS2 lattice. Such structural regularity of pillars results in a remarkable enhancement of porosity, as confirmed by nitrogen adsorption-desorption isotherms. The Langmuir specific surface area (186 m2 g-1) of the TiO2-pillared MoS2 has been determined to be remarkably larger than that (12 m 2 g-1) of the restacked MoS2. It is, therefore, evident that adequate intercalation of TiO2 nanoparticles into a MoS2 lattice gives rise to a highly porous structure. Ti K-edge extended X-ray absorption fine structure (EXAFS) analyses also indicate that the anatase nanopillars are stabilized in the interlayer space of MoS2 without any significant agglomeration. From Mo K-edge EXAFS studies, it has been found that the highly distorted octahedral structure of the host lattice in the as-prepared nanohybrid changes into a thermodynamically stable trigonal prismatic one upon heat treatment. © 2005 American Chemical Society. | - |
dc.language | English | - |
dc.title | An inorganic nanohybrid with high specific surface area: TiO 2-pillared MoS2 | - |
dc.type | Article | - |
dc.relation.issue | 13 | - |
dc.relation.volume | 17 | - |
dc.relation.index | SCIE | - |
dc.relation.index | SCOPUS | - |
dc.relation.startpage | 3492 | - |
dc.relation.lastpage | 3498 | - |
dc.relation.journaltitle | Chemistry of Materials | - |
dc.identifier.doi | 10.1021/cm0477220 | - |
dc.identifier.wosid | WOS:000230075800028 | - |
dc.identifier.scopusid | 2-s2.0-22944442282 | - |
dc.author.google | Paek S.-M. | - |
dc.author.google | Jung H. | - |
dc.author.google | Park M. | - |
dc.author.google | Lee J.-K. | - |
dc.author.google | Choy J.-H. | - |
dc.contributor.scopusid | 최진호(8044393000) | - |
dc.date.modifydate | 20190301081000 | - |