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Mechanistic insight into alcohol oxidation by high-valent iron-oxo complexes of heme and nonheme ligands

Title
Mechanistic insight into alcohol oxidation by high-valent iron-oxo complexes of heme and nonheme ligands
Authors
Na Y.O.Suh Y.Mi J.P.Mi S.S.Kim J.Nam W.
Ewha Authors
남원우김진흥서미숙
SCOPUS Author ID
남원우scopus; 김진흥scopus
Issue Date
2005
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
Angewandte Chemie - International Edition vol. 44, no. 27, pp. 4235 - 4239
Indexed
SCI; SCIE; SCOPUS WOS scopus
Document Type
Article
Abstract
(Chemical Equation Presented) Iron-mediated oxidation: High-valent iron(IV)-oxo complexes of heme and nonheme ligands are generated in situ and are used in mechanistic studies of alcohol oxidation (see scheme). It is proposed that the oxidation of alcohols occurs by an α-CH hydrogen atom abstraction followed by electron transfer. Porp = porphyrin. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
DOI
10.1002/anie.200500623
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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