Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김성진 | * |
dc.date.accessioned | 2018-05-18T08:14:59Z | - |
dc.date.available | 2018-05-18T08:14:59Z | - |
dc.date.issued | 2005 | * |
dc.identifier.issn | 0020-1669 | * |
dc.identifier.other | OAK-2818 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/243094 | - |
dc.description.abstract | A transition metal-containing Zintl phase, Sr2MnSb2, was prepared from a stoichiometric combination reaction of the elements in Sn flux, and its structure was determined by single-crystal X-ray diffraction methods. The compound crystallizes in the orthorhombic space group Pnma with a = 15.936(3) Å, b = 14.498(3) Å, c = 8.2646(17) Å, and Z = 12. The structure of Sr2MnSb2 is composed of corrugated layers of corner- and edge-shared MnSb4 tetrahedra. The basic building unit of the layer is a [Mn3Sb6]12- cluster composed of three edge-shared MnSb4 tetrahedra. These trinuclear clusters share four Sb vertexes to form a layer with cavities. Sr2+ cations are located at the inter-and intralayer space. Magnetic susceptibility measurements indicate an effective magnetic moment of 4.85 μB, a value smaller than what would be expected from Mn2+ ions. © 2005 American Chemical Society. | * |
dc.language | English | * |
dc.title | Sr2MnSb2: A new ternary transition metal zintl phase | * |
dc.type | Article | * |
dc.relation.issue | 14 | * |
dc.relation.volume | 44 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 4979 | * |
dc.relation.lastpage | 4982 | * |
dc.relation.journaltitle | Inorganic Chemistry | * |
dc.identifier.doi | 10.1021/ic048252e | * |
dc.identifier.wosid | WOS:000230555400017 | * |
dc.identifier.scopusid | 2-s2.0-22544452124 | * |
dc.author.google | Park S.-M. | * |
dc.author.google | Kim S.-J. | * |
dc.author.google | Kanatzidis M.G. | * |
dc.contributor.scopusid | 김성진(56812714700) | * |
dc.date.modifydate | 20240301081003 | * |