Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 김진흥 | * |
dc.contributor.author | 서미숙 | * |
dc.date.accessioned | 2018-05-18T08:14:50Z | - |
dc.date.available | 2018-05-18T08:14:50Z | - |
dc.date.issued | 2005 | * |
dc.identifier.issn | 0002-7863 | * |
dc.identifier.other | OAK-2911 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/243038 | - |
dc.description.abstract | Axial ligand substitution of a mononuclear nonheme oxoiron(IV) complex, [FeIV(O)(TMC)(NCCH3)]2+ (1) (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane), leads to the formation of new FeIV=O species with relatively intense electronic absorption features in the near-UV region. The presence of these near-UV features allowed us to make the first observation of Fe=O vibrations of S = 1 mononuclear nonheme oxoiron(IV) complexes by resonance Raman spectroscopy. We have also demonstrated that the reactivity of nonheme oxoiron(IV) intermediates is markedly influenced by the axial ligands. Copyright © 2005 AmericanChemical Society. | * |
dc.language | English | * |
dc.title | Axial ligand substituted nonheme FeIV=O complexes: Observation of near-UV LMCT bands and Fe=O Raman vibrations | * |
dc.type | Article | * |
dc.relation.issue | 36 | * |
dc.relation.volume | 127 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 12494 | * |
dc.relation.lastpage | 12495 | * |
dc.relation.journaltitle | Journal of the American Chemical Society | * |
dc.identifier.doi | 10.1021/ja0540573 | * |
dc.identifier.wosid | WOS:000232039100031 | * |
dc.identifier.scopusid | 2-s2.0-24744461128 | * |
dc.author.google | Sastri C.V. | * |
dc.author.google | Park M.J. | * |
dc.author.google | Ohta T. | * |
dc.author.google | Jackson T.A. | * |
dc.author.google | Stubna A. | * |
dc.author.google | Seo M.S. | * |
dc.author.google | Lee J. | * |
dc.author.google | Kim J. | * |
dc.author.google | Kitagawa T. | * |
dc.author.google | Munck E. | * |
dc.author.google | Que Jr. L. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | 김진흥(8580015800) | * |
dc.date.modifydate | 20240116111857 | * |