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Direct evidence for oxygen-atom exchange between nonheme oxoiron(IV) complexes and isotopically labeled water

Title
Direct evidence for oxygen-atom exchange between nonheme oxoiron(IV) complexes and isotopically labeled water
Authors
Seo M.S.In J.-H.Kim S.O.Oh N.Y.Hong J.Kim J.Que Jr. L.Nam W.
Ewha Authors
남원우김진흥서미숙
SCOPUS Author ID
남원우scopus; 김진흥scopus
Issue Date
2004
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
vol. 43, no. 18, pp. 2417 - 2420
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Rates of exchange: Evidence that non-heme oxoiron(IV) complexes exchange their oxygen atoms with H218O was obtained for the first time, by monitoring electrospray ionization mass spectral changes of the oxoiron(IV) species. The oxygen-atom exchange depended markedly on the amounts of H218O present and reaction temperatures but not on the presence of trans axial ligand (see scheme).
DOI
10.1002/anie.200353497
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자연과학대학 > 화학·나노과학전공 > Journal papers
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