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Dual-channel sensing of CO2: Reversible solution-gel transition and gelation-induced fluorescence enhancement
- Dual-channel sensing of CO2: Reversible solution-gel transition and gelation-induced fluorescence enhancement
- Zhang, Xin; Mu, Huifang; Li, Haimiao; Zhang, Yu; An, Meng; Zhang, Xuhong; Yoon, Juyoung; Yu, Haitao
- Ewha Authors
- SCOPUS Author ID
- Issue Date
- Journal Title
- SENSORS AND ACTUATORS B-CHEMICAL
- vol. 255, pp. 2764 - 2778
- Aroylhydrazone-derivatized organogelator; CO2 sensor; Anion-activated strategy; Aggregation-induced emission; Solution-to-gel transition
- ELSEVIER SCIENCE SA
- SCI; SCIE; SCOPUS
- It is imperative for various applications to develop new sensing systems in the visualization and detection of CO2. Here, several aroylhydrazone-derivatized organogelators have been prepared and developed as CO2 sensors via the anion-activated strategy. These new compounds can gel some of polar and apolar organic solvents to form stable organogels which have been well characterized by field emission scanning electron microscopy (FE-SEM), FT-IR spectroscopy, concentration- and temperature-dependent H-1 NMR spectra, PXRD, and UV-vis spectroscopy. In addition, they can show gelation-induced fluorescence enhancement performances which have been proven to derive from the aggregation-induced emission (AIE) effect. In particular, the fluoride anion-triggered solutions of the organogelators can permit naked-eye sensing of CO2 in air via the solution-to-gel transition. Besides, the developed gelation systems can also be used to provide quantitative means for CO2 stream through re-gelation induced fluorescence enhancement. Moreover, the reversibility of these sensing systems for the capture and release of CO2 enhances their applicable potential. (C) 2017 Elsevier B.V. All rights reserved.
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