Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김원석 | * |
dc.date.accessioned | 2018-01-11T16:30:37Z | - |
dc.date.available | 2018-01-11T16:30:37Z | - |
dc.date.issued | 2017 | * |
dc.identifier.issn | 1523-7060 | * |
dc.identifier.issn | 1523-7052 | * |
dc.identifier.other | OAK-21612 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/239700 | - |
dc.description.abstract | 3-Hydroxy-2-(trialkylsilyl)phenyl triflates are presented as new versatile hydroxyaryne precursors. These are base-activated aryne precursors induced via a C-sp(2)-to-O 1,3-Brook rearrangement. The reaction of various arynophiles and 3-trialkylsiloxybenzyne generated from 3-hydroxy-2-(trialkylsilyl)phenyl triflate efficiently afforded highly regioselective phenol derivatives. Furthermore, through crossover experiments, the intramolecular mechanism of silyl migration was demonstrated. | * |
dc.language | English | * |
dc.publisher | AMER CHEMICAL SOC | * |
dc.title | 3-Hydroxy-2-(trialkylsilyl)phenyl Triflate: A Benzyne Precursor Triggered via 1,3-C-sp(2)-to-O Silyl Migration | * |
dc.type | Article | * |
dc.relation.issue | 22 | * |
dc.relation.volume | 19 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 6224 | * |
dc.relation.lastpage | 6227 | * |
dc.relation.journaltitle | ORGANIC LETTERS | * |
dc.identifier.doi | 10.1021/acs.orglett.7b03160 | * |
dc.identifier.wosid | WOS:000416204300049 | * |
dc.identifier.scopusid | 2-s2.0-85034566030 | * |
dc.author.google | Kwon, Yong-Ju | * |
dc.author.google | Jeon, Young-Kyo | * |
dc.author.google | Sim, Ha-Bin | * |
dc.author.google | Oh, In-Young | * |
dc.author.google | Shin, Inji | * |
dc.author.google | Kim, Won-Suk | * |
dc.contributor.scopusid | 김원석(57203484044) | * |
dc.date.modifydate | 20240220102223 | * |