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자연과학대학
화학·나노과학전공
Journal papers
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Instantaneous Colorimetric and Fluorogenic Detection of Phosgene with a meso-Oxime-BODIPY
Title
Instantaneous Colorimetric and Fluorogenic Detection of Phosgene with a meso-Oxime-BODIPY
Authors
Kim T.-I.
;
Hwang B.
;
Bouffard J.
;
Kim Y.
Ewha Authors
Jean Bouffard
SCOPUS Author ID
Jean Bouffard
Issue Date
2017
Journal Title
Analytical Chemistry
ISSN
0003-2700
Citation
Analytical Chemistry vol. 89, no. 23, pp. 12837 - 12842
Publisher
American Chemical Society
Indexed
SCIE; SCOPUS
Document Type
Article
Abstract
The meso-oxime-substituted-1,3,5,7-tetramethyl BODIPY (1-oxime) was developed into a colorimetric and fluorogenic probe to selectively detect and quantify phosgene. The fast (<10 s) and sensitive (LOD = 0.09 ppb) phosgene detection is achieved by the conversion of the meso-oxime to the meso-nitrile, resulting in a large fluorescence turn-on response. The utility of 1-oxime was established for the visual detection of phosgene in solution and in a practical solid-state platform, making it a suitable candidate for on-site monitoring of phosgene gas exposure in the workplace. © 2017 American Chemical Society.
DOI
10.1021/acs.analchem.7b03316
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