DSpace at EWHA: The unusual hydridicity of a cobalt bound Si-H moiety

View : 788 Download: 0

Full metadata record

DC Field	Value	Language
dc.contributor.author	김선희	*
dc.date.accessioned	2017-06-27T01:06:08Z	-
dc.date.available	2017-06-27T01:06:08Z	-
dc.date.issued	2016	*
dc.identifier.issn	1359-7345	*
dc.identifier.issn	1364-548X	*
dc.identifier.other	OAK-19102	*
dc.identifier.uri	https://dspace.ewha.ac.kr/handle/2015.oak/235356	-
dc.description.abstract	A paramagnetic cobalt-SiH intermediate possessing the Co-(eta(1)-H-Si) moiety was studied using various spectroscopic techniques. Frozen solution ENDOR experiments show a Co-H distance of similar to 1.53 angstrom and a Si-Co-H angle of similar to 15 degrees, whereas XRD data suggest a TBP geometry about a Co(II) centre. Its stepwise deprotonation with base followed by dehalogenation was identified experimentally and theoretically.	*
dc.language	English	*
dc.publisher	ROYAL SOC CHEMISTRY	*
dc.title	The unusual hydridicity of a cobalt bound Si-H moiety	*
dc.type	Article	*
dc.relation.issue	60	*
dc.relation.volume	52	*
dc.relation.index	SCIE	*
dc.relation.index	SCOPUS	*
dc.relation.startpage	9367	*
dc.relation.lastpage	9370	*
dc.relation.journaltitle	CHEMICAL COMMUNICATIONS	*
dc.identifier.doi	10.1039/c6cc03983a	*
dc.identifier.wosid	WOS:000379882200009	*
dc.identifier.scopusid	2-s2.0-84979226400	*
dc.author.google	Kim, Jin	*
dc.author.google	Kim, Yujeong	*
dc.author.google	Sinha, Indranil	*
dc.author.google	Park, Koeun	*
dc.author.google	Kim, Sun Hee	*
dc.author.google	Lee, Yunho	*
dc.contributor.scopusid	김선희(57205324645;57196230818)	*
dc.date.modifydate	20240130093611	*