Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 최진호 | - |
dc.date.accessioned | 2017-04-25T01:04:12Z | - |
dc.date.available | 2017-04-25T01:04:12Z | - |
dc.date.issued | 2016 | - |
dc.identifier.issn | 2365-6549 | - |
dc.identifier.other | OAK-20458 | - |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/234987 | - |
dc.description.abstract | Highly crystalline nanoporous GaN (NP-GaN) materials have been synthesized for the first time by the transformation of novel diamino tetrazine based mesoporous carbon nitride (MCN-4) having very high nitrogen content (N/C ratio of 1.8) and GaCl3 through the unique reactive hard templating approach. Powder XRD and HRTEM analysis show that the prepared NP-GaN is highly pure and possesses excellent crystallinity. N-2 adsorption analysis confirm that the samples exhibit mesoporosity with excellent textural parameters including high specific surface areas. It is also demonstrated that NP-GaN materials show excellent catalytic activity in the Friedel-Crafts hexanoylation of benzene by using hexanoyl chloride (HC) with excellent conversion of HC. The activity of the NP-GaN is also compared with MCN-4, bulk Ga2O3 and GaN. Among the materials studied, NP-GaN shows the highest catalytic performance in the above mentioned reaction with excellent conversion of HC and product selectivity to hexanophenone. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | Gallium nitride | - |
dc.subject | mesoporous carbon nitride | - |
dc.subject | templating method | - |
dc.subject | heterogeneous catalysis | - |
dc.subject | Friedel-Crafts | - |
dc.title | Facile Synthesis of Crystalline Nanoporous GaN Templated by Nitrogen Enriched Mesoporous Carbon Nitride for Friedel-Crafts Reaction | - |
dc.type | Article | - |
dc.relation.issue | 19 | - |
dc.relation.volume | 1 | - |
dc.relation.index | SCIE | - |
dc.relation.startpage | 6062 | - |
dc.relation.lastpage | 6068 | - |
dc.relation.journaltitle | CHEMISTRYSELECT | - |
dc.identifier.doi | 10.1002/slct.201601545 | - |
dc.identifier.wosid | WOS:000395432100002 | - |
dc.author.google | Talapaneni, Siddulu Naidu | - |
dc.author.google | Park, Dae-Hwan | - |
dc.author.google | Choy, Jin-Ho | - |
dc.author.google | Ramadass, Kavitha | - |
dc.author.google | Elzatahry, Ahmed | - |
dc.author.google | Al Balawi, Ahmed S. | - |
dc.author.google | Al-Enizi, Abdullah M. | - |
dc.author.google | Mori, Toshiyuki | - |
dc.author.google | Vinu, Ajayan | - |
dc.contributor.scopusid | 최진호(8044393000) | - |
dc.date.modifydate | 20190301081000 | - |