Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.date.accessioned | 2017-02-15T08:02:33Z | - |
dc.date.available | 2017-02-15T08:02:33Z | - |
dc.date.issued | 2007 | * |
dc.identifier.issn | 0022-3263 | * |
dc.identifier.other | OAK-4160 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/234411 | - |
dc.description.abstract | (Chemical Equation Presented) Mechanistic studies of the aromatic hydroxylation by high-valent iron(IV)-oxo porphyrin π-cation radicals revealed that the aromatic oxidation involves an initial electrophilic attack on the π-system of the aromatic ring to produce a tetrahedral radical or cationic σ-complex. The mechanism was proposed on the basis of experimental results such as a large negative Hammett ρ value and an inverse kinetic isotope effect. By carrying out isotope labeling studies, the oxygen in oxygenated products was found to derive from the iron-oxo porphyrin intermediates. © 2007 American Chemical Society. | * |
dc.language | English | * |
dc.title | Mechanistic insight into the aromatic hydroxylation by high-valent iron(IV)-oxo porphyrin π-cation radical complexes | * |
dc.type | Article | * |
dc.relation.issue | 16 | * |
dc.relation.volume | 72 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 6301 | * |
dc.relation.lastpage | 6304 | * |
dc.relation.journaltitle | Journal of Organic Chemistry | * |
dc.identifier.doi | 10.1021/jo070557y | * |
dc.identifier.wosid | WOS:000248344400053 | * |
dc.identifier.scopusid | 2-s2.0-34547624183 | * |
dc.author.google | Kang M.-J. | * |
dc.author.google | Woon J.S. | * |
dc.author.google | Han A.-R. | * |
dc.author.google | Choi Y.S. | * |
dc.author.google | Jang H.G. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.date.modifydate | 20240116111857 | * |