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Tetra-ethyl-ammonium dichlorido[N,N′-(o-phenyl-ene)bis-(isoquinoline- 2-carboxamidato)-4 N]cobaltate(III)

Title
Tetra-ethyl-ammonium dichlorido[N,N′-(o-phenyl-ene)bis-(isoquinoline- 2-carboxamidato)-4 N]cobaltate(III)
Authors
Lee D.N.Lee E.Y.Kim C.Kim S.-J.Kim Y.
Ewha Authors
김성진김영미
SCOPUS Author ID
김성진scopus; 김영미scopus
Issue Date
2007
Journal Title
Acta Crystallographica Section E: Structure Reports Online
ISSN
1600-5368JCR Link
Citation
vol. 63, no. 7, pp. m1949 - m1950
Indexed
SCOPUS WOS scopus
Abstract
In the title compound, (C8H20N)[Co(C26H16N4O2)Cl2], the four N atoms of the N,N′-(o-phenyl-ene)bis-(isoquinoline-2-carboxamidate) (biqb2-) ligand form the equatorial plane of a distorted octa-hedral coordination environment around the CoIII ion, while two chloride ligands are axially coordinated. The Co - Namide distances are significantly shorter than the Co - Npyrid-yl distances. The dihedral angle between the two isoquinoline fused-ring systems is 25.72 (7)°. The crystal structure is stabilized, in part, by inter-molecular Ccation - H⋯Cl and Cisoquinoline - H⋯Cl hydrogen bonds. © International Union of Crystallography 2007.
DOI
10.1107/S1600536807029091
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자연과학대학 > 화학·나노과학전공 > Journal papers
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