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Chemistry of mass-selected Au clusters deposited on sputter-damaged HOPG surfaces: The unique properties of Au8 clusters

Title
Chemistry of mass-selected Au clusters deposited on sputter-damaged HOPG surfaces: The unique properties of Au8 clusters
Authors
Lim D.C.Dietsche R.Bubek M.Ketterer T.Gantefor G.Kim Y.D.
Ewha Authors
김영독
Issue Date
2007
Journal Title
Chemical Physics Letters
ISSN
0009-2614JCR Link
Citation
vol. 439, no. 41370, pp. 364 - 368
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Mass-selected Au clusters consisting of less than 10 atoms were deposited on sputter-damaged HOPG surfaces. Oxidation and reduction of the Au clusters were studied using X-ray photoelectron spectroscopy. Only Au8 can be significantly oxidized by oxygen and reduced by CO, and the result is different from those for Au clusters deposited on silica. The chemical properties of mass-selected clusters are dissimilar to those of Au nanoparticles larger ∼2-3 nm. STM studies on Au7 suggest that Au7 exists as individual clusters rather than forming larger particles on the surface. © 2007 Elsevier B.V. All rights reserved.
DOI
10.1016/j.cplett.2007.04.001
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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