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A new self-assembled inorganic-organic hybrid layered compound containing hexarhenium cluster: [MV][{Mn(CH3OH)2}{Re6Se8(CN)6}]

Title
A new self-assembled inorganic-organic hybrid layered compound containing hexarhenium cluster: [MV][{Mn(CH3OH)2}{Re6Se8(CN)6}]
Authors
Kim S.Kim Y.Lee J.Shin W.Lee M.Kim S.-J.
Ewha Authors
김성진이민영김영미
SCOPUS Author ID
김성진scopus; 이민영scopus; 김영미scopus
Issue Date
2007
Journal Title
Inorganica Chimica Acta
ISSN
0020-1693JCR Link
Citation
vol. 360, no. 6, pp. 1890 - 1894
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A new layered compound, [MV][{Mn(CH3OH)2}{Re6Se8(CN)6}] (1) consists of a layer alternately knitted by hexarhenium cluster and Mn complex, and MV2+ cations (methyl viologen dication = 1,1′-dimethyl-4,4′-bipyridilium dication) reside between the layers. The title compound 1 is the first layered framework containing cyano-hexarhenium clusters with photoactive guest molecules, MV2+. The MV2+ can be partly exchanged by H2TMB2+ (N,N,N′,N′-tetramethylbenzidine dication) to form a compound [H2TMB2+]x[MV2+]1-x [{Mn(CH3OH)2}{Re6Se8(CN)6}] (2) showing an electronic interaction between the layered framework and [H2TMB]2+ cation. © 2006 Elsevier B.V. All rights reserved.
DOI
10.1016/j.ica.2006.09.028
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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