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A new organic-inorganic hybrid framework containing octahedral hexarhenium cluster and its transformation by ligand exchange

Title
A new organic-inorganic hybrid framework containing octahedral hexarhenium cluster and its transformation by ligand exchange
Authors
Kim S.Kim Y.Kal Y.Kim S.-J.
Ewha Authors
김성진김영미
SCOPUS Author ID
김성진scopus; 김영미scopus
Issue Date
2007
Journal Title
Inorganica Chimica Acta
ISSN
0020-1693JCR Link
Citation
vol. 360, no. 6, pp. 1870 - 1874
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A new organic-inorganic hybrid solid with 3-D framework, [Mn(DMF)3]2[Re6Se8(CN)6] (1), has been synthesized and transformed to [H][Mn(salen)]3[Re6Se8(CN)6] (2) by a ligand exchange. Hexarhenium chalcocyanide clusters are closest packed in cubic symmetry for 1 and rhombohedral symmetry for 2. The manganese complexes in the interstitial sites are three-coordinated to the rhenium cluster in 1 and two-coordinated in 2. © 2006 Elsevier B.V. All rights reserved.
DOI
10.1016/j.ica.2006.09.031
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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