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Pd(II) polymeric compounds directed by intermolecular C-H⋯X-C interactions (X = F, Cl): Suzuki-Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex

Title
Pd(II) polymeric compounds directed by intermolecular C-H⋯X-C interactions (X = F, Cl): Suzuki-Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex
Authors
Lee J.H.Kim H.J.Choi Y.W.Lee Y.M.Park B.K.Kim C.Kim S.-J.Kim Y.
Ewha Authors
김성진김영미
SCOPUS Author ID
김성진scopus; 김영미scopus
Issue Date
2007
Journal Title
Polyhedron
ISSN
0277-5387JCR Link
Citation
vol. 26, no. 7, pp. 1388 - 1396
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
New palladium polymeric compounds containing novel tetradentate halogen-substituted 6Me2bpX2- ligands (6Me2bpX2- = 1,2-bis(6-methylpyridine-2-carboxamide) halobenzene dianion, X = F for 4, Cl for 5) were constructed by non-classical C-H⋯X-C interactions, and the novel catalyst 5 was used to carry out Suzuki coupling reactions with aryl iodides and aryl boronic acids under mild conditions. © 2006 Elsevier Ltd. All rights reserved.
DOI
10.1016/j.poly.2006.11.020
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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