Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 서미숙 | * |
dc.date.accessioned | 2017-02-15T08:02:07Z | - |
dc.date.available | 2017-02-15T08:02:07Z | - |
dc.date.issued | 2007 | * |
dc.identifier.issn | 1433-7851 | * |
dc.identifier.other | OAK-3896 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/234283 | - |
dc.description.abstract | The active oxidant that oxygenates organic substrates is an iron(IV) oxo intermediate, namely, [(tpa)FeIV(O)(CH3CN)]2+ (2), which is formed through O-O bond homolysis, according to experimental and computational studies on the reactivity of nonheme iron(III) alkylperoxo complex [(tpa)FeIII(OOtBu)(CH3CN)]2+ (1), which was shown to be a sluggish electrophilic oxidant that is incapable of oxygenating organic substrates. tpa = tris(2-pyridylmethyl)amine. (Chemical Equation Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA. | * |
dc.language | English | * |
dc.title | Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions | * |
dc.type | Article | * |
dc.relation.issue | 13 | * |
dc.relation.volume | 46 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 2291 | * |
dc.relation.lastpage | 2294 | * |
dc.relation.journaltitle | Angewandte Chemie - International Edition | * |
dc.identifier.doi | 10.1002/anie.200604219 | * |
dc.identifier.wosid | WOS:000245232800031 | * |
dc.identifier.scopusid | 2-s2.0-34250164725 | * |
dc.author.google | Seo M.S. | * |
dc.author.google | Kamachi T. | * |
dc.author.google | Kouno T. | * |
dc.author.google | Murata K. | * |
dc.author.google | Park M.J. | * |
dc.author.google | Yoshizawa K. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.date.modifydate | 20240116111857 | * |