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Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2′-dipyridylamine (Hdpa): Novel heterogeneous catalytic activities

Title
Anion effect on construction of zinc(II) coordination polymer with a chelating ligand 2,2′-dipyridylamine (Hdpa): Novel heterogeneous catalytic activities
Authors
Lee Y.M.Hong S.J.Kim H.J.Lee S.H.Kwak H.Kim C.Kim S.-J.Kim Y.
Ewha Authors
김성진김영미
SCOPUS Author ID
김성진scopus; 김영미scopus
Issue Date
2007
Journal Title
Inorganic Chemistry Communications
ISSN
1387-7003JCR Link
Citation
vol. 10, no. 3, pp. 287 - 291
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The reaction of ZnSO4 with 2,2′-dipyridylamine (Hdpa) results in a coordination polymer 1 while other zinc(II) salts (bromide 2 or benzoateanions 3) produce usually monomers which can generate hydrogen-bonded polymers. The coordination polymer 1 and hydrogen-bonded polymer 2 have shown, surprisingly, unusual heterogeneous catalytic activities on transesterification reaction of esters, but the monomeric compound 3 catalyzed the reaction homogeneously. © 2006 Elsevier B.V. All rights reserved.
DOI
10.1016/j.inoche.2006.11.001
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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