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A new Co(II) complex with N,O-donor Schiff base: Synthesis, structure and characterization

Title
A new Co(II) complex with N,O-donor Schiff base: Synthesis, structure and characterization
Authors
Xu L.Mironov Yu.V.Qi X.Kim S.-J.
Ewha Authors
김성진
SCOPUS Author ID
김성진scopus
Issue Date
2006
Journal Title
Journal of Structural Chemistry
ISSN
0022-4766JCR Link
Citation
vol. 47, no. 5, pp. 998 - 1001
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A new Co(II) complex with tridentate Schiff base ligand with a N,N,O donor set has been synthesized and characterized by single X-ray technique and spectroscopic techniques. The thermochemical properties have been studied. X-ray structure analysis of the title compound Co(II)L2 [HL = 2-methyl-6-(2′-hydroxybenzylideneamino) pyridine] shows that the polyhedron around Co(II) is a distorted tetrahedron, and the self-assembly via intermolecular π-π interactions leads to a three-dimensional network. Crystal data for the title complex C26H22CoN 4O2: Monoclinic, space group Ia, a = 11.741(7) Å, b = 8.149(5) Å, c = 22.764(16) Å, β = 98.530(12)°, V = 2154(2) Å3, Z = 4. © 2006 Springer Science+Business Media, Inc.
DOI
10.1007/s10947-006-0418-1
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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