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Reversible formation of iodosylbenzene-iron porphyrin intermediates in the reaction of oxoiron(IV) porphyrin π-cation radicals and iodobenzene

Title
Reversible formation of iodosylbenzene-iron porphyrin intermediates in the reaction of oxoiron(IV) porphyrin π-cation radicals and iodobenzene
Authors
Nam W.Choi S.K.Lim M.H.Rohde J.-U.Kim I.Kim J.Kim C.Que Jr. L.
Ewha Authors
남원우
SCOPUS Author ID
남원우scopus
Issue Date
2003
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
vol. 42, no. 1, pp. 109 - 111
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The electronic nature of iron porphyrin complexes and iodobenzene derivatives markedly influences the formation of iodosylbenzene-iron(III) porphyrin intermediates 2, which are generated in the reaction of oxoiron(IV) porphyrin cation radicals 1 and iodobenzene. Epoxidation of olefins by 2 affords high yields of epoxide products.
DOI
10.1002/anie.200390036
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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